Қазақ ұлттық қыздар педагогикалық университеті / Казахский национальный женский педагогический университет

Постоянный URI для этого сообществаhttps://cris.qyzpu.edu.kz/handle/123456789/1

Просмотр

Фильтры

2021 - 20232

Настройки

Автор: search.filters.author.Juozas V. Gražulevičius

Результаты поиска

Показано: 1 - 2 из 2
  • Загрузка...
    Изображение-миниатюра
    Некоторые метрики заблокированы вашими 
    настройками согласия
    Тип записи:Публикация,
    Impact of Neodymium and Scandium Ionic Radii on Sorption Dynamics of Amberlite IR120 and AB-17-8 Remote Interaction
    (Multidisciplinary Digital Publishing Institute, 2021-09-18)
    Talkybek Jumadilov
    ;
    Bakytgul Totkhuskyzy
    ;
    Zamira Malimbayeva
    ;
    R. G. Kondaurov
    ;
    А. М. Imangazy
    The aim of the work is to provide a comparative study of influence of ionic radii of neodymium and scandium ions on their sorption process from corresponding sulfates by individual ion exchangers Amberlite IR120, AB-17-8 and interpolymer system Amberlite IR120-AB-17-8. Experiments were carried out by using the following physicochemical methods of analysis: conductometry, pH-metry, colorimetry, and atomic-emission spectroscopy. Ion exchangers in the interpolymer system undergo remote interactions with a further transition into highly ionized state. There is the formation of optimal conformation in the structure of the initial ion exchangers. A significant increase of ionization of the ion-exchange resins occurs at molar ratio of Amberlite IR120:AB-17-8 = 5:1. A significant increase of sorption properties is observed at this ratio due to the mutual activation of ion exchangers. The average growth of sorption properties in interpolymer system Amberlite IR120:AB-17-8 = 5:1 is over 90% comparatively to Amberlite IR120 and almost 170% comparatively to AB-17-8 for neodymium ions sorption; for scandium ions sorption the growth is over 65% comparatively to Amberlite IR120 and almost 90% comparatively to AB-17-8. A possible reason for higher sorption of neodymium ions in comparison with scandium ions is maximum conformity of globes of internode links of Amberlite IR120 and AB-17-8 after activation to sizes of neodymium sulfate in an aqueous medium.
    Цитирования (OpenAlex) 14Цитирования (OpenCitations) 9
  • Загрузка...
    Изображение-миниатюра
    Некоторые метрики заблокированы вашими 
    настройками согласия
    Тип записи:Публикация,
    Anomalous Sorption of Yttrium Ions by the Mutual Activated Hydrogels in the Interpolymer System of Poly(Methacrylic Acid) and Poly(4-Vinylpyridine)
    (Lviv Polytechnic National University, 2023-03-26)
    Talkybek Jumadilov
    ;
    Bakytgul Totkhuskyzy
    ;
    А. М. Imangazy
    ;
    Juozas V. Gražulevičius
    This paper considers the effect of mutual activation of poly(methacrylic acid) (PMAA) and poly-(4 vinylpyridine) (P4VP) hydrogels during their remote interaction on the degree of yttrium ions sorption from an aqueous medium. Electrochemical properties were studied by conductometry and pH measurements to predict the activation possibility of these hydrogels. pH measurements showed that at 0.1 hour, the pH values were the lowest, indicating a high content of H+ ions in the aqueous solution. An increase in the interaction time to 24 hours leads to an increase in pH values, indicating a decrease in the content of H+ ions in the solution. The dependences of the specific electrical conductivity were studied. The experiments showed that the maximum values were observed at the ratios of 3 : 3 and 1 : 5 (gPMAA : gP4VP), which coincided with the result of pH measurements. The obtained results indicate the significant changes occurred in the electrochemical and conformational values of the initial macromolecules in the interpolymer system. Our research confirms the presence of remote interaction between hydrogels and their mutual activation.
    Цитирования (OpenAlex) 8Цитирования (OpenCitations) 5